SYNTHESIS AND MOLECULAR-STRUCTURE OF 3-BROMO-TRANS-2,6-DIALLYL-DELTA(3)-PIPERIDEINE HYDROCHLORIDE

被引：6

作者：

BUBNOV, YN ^{[1
]}

SHAGOVA, EA ^{[1
]}

EVCHENKO, SV ^{[1
]}

DEKAPRILEVICH, MO ^{[1
]}

STRUCHKOV, YT ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 04期

关键词：

REDUCTIVE ALLYLATION; ALLYLBORATION; TRIALLYLBORANE; PYRIDINES; X-RAY DIFFRACTION ANALYSIS; 3-BROMO-2,6-DIALLYL-DELTA(3)-PIPERIDEINES; TRANS- TO CIS-ISOMERIZATION;

D O I：

10.1007/BF00699843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of 3-bromo-trans-2,6-diallyl-Delta(3)-piperideine hydrochloride was determined by X-ray diffraction analysis. The corresponding base was prepared by reductive diallylation of 3-bromopyridine with triallylborane. 3-Bromo-cis-2,6-diallyl-Delta(3)-piperideine 3 was prepared by heating trans-isomer 2 with traillylborane at 130 degrees C followed by deboronation of the resulting aminoborane with a solution of sodium hydroxide.

引用

页码：657 / 659

页数：3

共 5 条

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