RADICAL REACTIONS IN ORGANOBORON CHEMISTRY .2. INTERMOLECULAR AND INTRAMOLECULAR ADDITION OF CARBON-CENTERED RADICALS TO ALKENYLBORANES

被引：61

作者：

GUENNOUNI, N ^{[1
]}

LHERMITTE, F ^{[1
]}

COCHARD, S ^{[1
]}

CARBONI, B ^{[1
]}

机构：

[1] UNIV RENNES 1,RECH PHYSICOCHIM STRUCT GRP,CNRS,URA 704,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON | 1995年 / 51卷 / 25期

关键词：

D O I：

10.1016/0040-4020(95)00358-F

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intermolecular addition of carbon centered radicals to alkenylboranes has been studied. The influence of the olefin and boron substituents on the reactivity and the regioselectivity was determined. Competitive experiments were carried out to estimate the relative reactivity of a series of vinylboranes and other electron deficient alkenes. Intramolecular versions of these additions were also described as well as some further transformations of selected adducts.

引用

页码：6999 / 7018

页数：20

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