1-(PI-CYCLOPENTADIENYLIRON DICARBONYL)PROPYNE

被引：61

作者：

JOLLY, PW

PETTIT, R

机构：

[1] Department of Chemistry, The University of Texas, Austin

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(00)88703-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of sodium π-cyclopentadienyliron dicarbonyl with 3-bromopropyne yields 3-(π-cyclopentadienyliron dicarbonyl)propyne; the latter compound undergoes facile acid catalyzed isomerization to give 1-(π-cyclopentadienyliron dicarbonyl)propyne. Various nucleophiles, e.g., acetate and water, react with the intermediate complex presumably involved in the rearrangement process. © 1968.

引用

页码：491 / &

共 20 条

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