PROTON MAGNETIC RESONANCE AND INFRARED STUDIES OF CIS AND TRANS ISOMERS OF A MONOSUBSTITUTED FORMANILIDE

被引：31

作者：

SIDDALL, TH

STEWART, WE

MARSTON, AL

机构：

[1] Savannah River Laboratory, E. I. du Pont de Nemours and Co., Aiken

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 06期

关键词：

D O I：

10.1021/j100852a044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pure cis and trans isomers of o-methylformanilide were isolated. When the amide dissolved in chloroform, an equilibrium cis:trans isomer ratio of 3:1 was established. The kinetics of the cis-trans equilibrium at several temperatures in deuteriochloroform were studied by proton magnetic resonance. Infrared studies of the cis and trans isomers were made, and band assignments for the amide vibrations are given.

引用

页码：2135 / &

共 24 条

[1]

BELLAMY LJ, 1958, INFRARED SPECTRA COM, P209

[2] CIS-TRANS ISOMERISM FORMANILIDE [J].