RADICAL TRANSPORT REACTION - CONCURRENT TRANSFER OF ELECTRON AND PROTON

被引：3

作者：

ICHIKAWA, J ^{[1
]}

SONODA, T ^{[1
]}

KOBAYASHI, H ^{[1
]}

机构：

[1] KYUSHU UNIV, INST ADV MAT STUDY, KASUGA, FUKUOKA 816, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1988年 / 61卷 / 08期

关键词：

Positive ions - Reduction;

D O I：

10.1246/bcsj.61.2923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Concurrent transport of electron and proton on the same molecule; formal hydrogen-transfer reaction, is successfully realized in aprotic media by using l-butyl-4,4′-bipyridinium cation radical (BuPPH+), which is prepared from l-butyl-4-(4-pyridyl)pyridinium ion. Hydrogen reduction with BuPPH+ was discriminated from electron reduction with octylviologen cation radical by the chemoselective reduction preferring enedione to vzc-dibromide in aprotic media. © 1988 The Chemical Society of Japan.

引用

页码：2923 / 2926

页数：4

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