ETA-CYCLOHEPTATRIENYL TUNGSTEN CHEMISTRY

被引：10

作者：

GREEN, MLH

NG, DKP

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 16期

关键词：

D O I：

10.1039/c39920001116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of WCl6 with sodium amalgam in the presence of cycloheptatriene gives [W(eta-C7H7)(eta-C7H9)], which is a precursor to the compounds [W(eta-C7H7)LX2], [W(eta-C7H7)L2X], where L = tertiary phosphines or acetonitrile and X = halogen, [W(eta-C7H7)(eta-C5H4R)], R = H, Me, and [W(eta-C7H7)(eta-C9H7)].

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页码：1116 / 1117

页数：2

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