CHIRAL-SYMMETRY-BREAKING IN NONEQUILIBRIUM CHEMICAL-SYSTEMS - THE RACEMIZATION INFLUENCE

被引：5

作者：

CATTANI, M

TOME, T

机构：

[1] Instituto de Fisica, Universidade de São Paulo, São Paulo, S.P., 20516-01498, Caixa Postal

来源：

ORIGINS OF LIFE AND EVOLUTION OF THE BIOSPHERE | 1993年 / 23卷 / 02期

关键词：

D O I：

10.1007/BF01581877

中图分类号：

Q [生物科学];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The open chemical nonequilibrium model, proposed by Kondepudi and Nelson to study the chiral-symmetry-breaking phenomenum, is analysed by the inclusion of the racemization process responsible for the interconversion of left- and right-enantiomers. We study the steady states of the chemical system as a function of the matter pumping and of the racemization rate.

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页码：125 / 136

页数：12

相关论文

共 16 条

[1] RACEMIZATION AND THE ORIGIN OF OPTICALLY-ACTIVE ORGANIC-COMPOUNDS IN LIVING ORGANISMS [J].

BADA, JL ;

MILLER, SL .

BIOSYSTEMS, 1987, 20 (01) :21-26

[2] ENVIRONMENT RACEMIZATION - A 2-LEVEL APPROACH [J].

CATTANI, M .

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1991, 46 (06) :507-511

[3] INSTABILITY OF TUNNELING AND THE CONCEPT OF MOLECULAR-STRUCTURE IN QUANTUM-MECHANICS - THE CASE OF PYRAMIDAL MOLECULES AND THE ENANTIOMER PROBLEM [J].

CLAVERIE, P ;

JONALASINIO, G .

PHYSICAL REVIEW A, 1986, 33 (04) :2245-2253

[4] CHIRAL RESOLUTIONS, ASYMMETRIC-SYNTHESIS AND AMPLIFICATION OF ENANTIOMERIC EXCESS [J].

DEMIN, M ;

LEVY, G ;

MICHEAU, JC .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1988, 85 (05) :603-619

[5]

DICKERSON RE, 1978, SCI AM, V239, P62

[6] CONSERVATION OF OPTICAL PURITY OF AMINO-ACIDS - A PRINCIPAL PROBLEM IN BIOCHEMICAL AND PROTOBIOCHEMICAL SYSTEMS [J].

DOSE, K .

ORIGINS OF LIFE AND EVOLUTION OF BIOSPHERES, 1981, 11 (1-2) :165-171

[7] ON THE TIME-DEPENDENCE OF OPTICAL-ACTIVITY [J].

HARRIS, RA ;

STODOLSKY, L .

JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (04) :2145-2155

[8] SENSITIVITY OF NON-EQUILIBRIUM SYSTEMS [J].

KONDEPUDI, DK ;

PRIGOGINE, I .

PHYSICA A, 1981, 107 (01) :1-24

[9] CHIRAL-SYMMETRY-BREAKING STATES AND THEIR SENSITIVITY IN NONEQUILIBRIUM CHEMICAL-SYSTEMS [J].

KONDEPUDI, DK ;

NELSON, GW .

PHYSICA A, 1984, 125 (2-3) :465-496

[10] WEAK NEUTRAL CURRENTS AND THE ORIGIN OF BIOMOLECULAR CHIRALITY [J].

KONDEPUDI, DK ;

NELSON, GW .

NATURE, 1985, 314 (6010) :438-441