BENZENE-1,2,4,5-TETRATIOLATO 2-MOIETY COMPLEXES OF TITANOCENE-ZIRCONOCENE-HAFNOCENE SYSTEM

被引：15

作者：

KOPF, H

BALZ, H

机构：

[1] Institut für Anorganische, Analytische Chemie der Technischen Universität Berlin, D-1000 Berlin 12

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 387卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)87301-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the metallocene dichlorides M(η5-C5H4R)2Cl2 (R = H; M = Ti, 1a; Zr, 1b; Hf, 1c. R = Si(CH3)3; M = Ti, 1d) with 1,2,4,5-tetramercaptobenzene and triethylamine or 1,2,4,5-tetrasodium tetramercaptobenzene, gives the new chelate complexes M(η5-C5H4R)2S2C6H2S2(η5-C5H4R)2M (R = H; M = Ti, 2a; Zr, 2b; Hf, 2c. R = Si(CH3)3; M = Ti, 2d). The new complexes have been characterized by 1H NMR, IR and mass spectroscopy. The activation energy for the ring inversion of 2d has been determined by temperature-dependent 1H NMR spectroscopy in solution. © 1990.

引用

页码：77 / 81

页数：5

共 9 条

[1]

BURNS RP, 1979, ADV INORG CHEM, V22, P303

[2] METAL POLY(BENZODITHIOLENES) [J].