NEW LIQUID-CRYSTAL COMPOUND - (+)-4-ALKOXYCARBONYLPHENYL 4-[5-(2-METHYLBUTYL)-1,3-OXATHIAN-2-YL]BENZOATE

被引:13
作者
HARAMOTO, Y
KAMOGAWA, H
机构
[1] Department of Applied Chemistry, Yamanashi University, Takeda 4
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1993年 / 226卷
关键词
1,3-OXATHIANE; PHASE TRANSITION; LIQUID CRYSTAL;
D O I
10.1080/10587259308028794
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New liquid crystal compound: (+)-4-Alkoxycarbonylphenyl-4-[5-(2-methylbutyl)-1,3-oxathiane-2-yl]benzoates (11) was synthesized. The mesomorphic behavior of this compound is compared with those of (+)-4-(2-methylbutoxycarbonyl)phenyl 4-(5-alkyl-1,3-oxathian-2-yl)benzoates (12), and (+)-4-alkoxy-carbonylphenyl 4-[5-(2-methylbutyl)-1,3-dioxan-2-yl]-benzoates (13), and (+)-4-Alkoxyphenyl 4-[5-(2-methylbutyl)-1,3-oxathian-2-yl]benzoates (14). Transition temperatures to the isotropic state for compound 11 were lower than those for the corresponding compounds 12 or 13. Though compound 11 exhibited the cholesteric phase, compound 12 exhibited the smectic phase. These features seem to originate in the wider molecular width of compound 11. Transition temperatures to the isotropic state for compound 11 are lower than those for 14. In this case, the difference of partial molecular width caused by carbonyl group seem to be main factor.
引用
收藏
页码:115 / 122
页数:8
相关论文
共 22 条
[1]  
Demus D., 1978, TEXTURES LIQUID CRYS
[2]  
DEMUS D, 1979, Patent No. 160916
[3]  
Gray V. G. W., 1984, SMECTIC LIQUID CRYST
[4]   LIQUID-CRYSTAL MATERIALS WITH SULFUR-ATOMS INCORPORATED IN THE PRINCIPAL STRUCTURE .5. NEW LIQUID-CRYSTAL COMPOUNDS - 2,5-DIARYL-1,3-OXATHIANES [J].
HARAMOTO, Y ;
SANO, M ;
KAMOGAWA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (05) :1337-1340
[5]   2-(PARA-CYANOPHENYL)-5-ALKYL-1,3-DITHIANES IN LIQUID-CRYSTAL MIXTURES [J].
HARAMOTO, Y ;
KAMOGAWA, H .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 131 (1-2) :101-107
[6]   2-(PARA-CYANOPHENYL)-5-ALKYL-1,3-OXATHIANES IN LIQUID-CRYSTAL MIXTURE [J].
HARAMOTO, Y ;
KAMOGAWA, H .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 131 (3-4) :201-207
[7]  
Haramoto Y., 1988, Molecular Crystals and Liquid Crystals Letters Section, V5, P117
[8]   LIQUID-CRYSTAL MATERIALS WITH SULFUR-ATOMS INCORPORATED IN THE PRINCIPAL STRUCTURE .2. NEW LIQUID-CRYSTAL COMPOUNDS - 2-SUBSTITUTED-5-(PARA-SUBSTITUTED PHENYL)-1,3-DITHIANES [J].
HARAMOTO, Y ;
AKAZAWA, K ;
KAMOGAWA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (11) :3173-3176
[9]   NEW FERROELECTRIC LIQUID-CRYSTAL MATERIALS - (+)-4-(2-METHYLBUTOXYCARBONYL)-PHENYL 4-(5-ALKYL-1,3-DIOXAN-2-YL)BENZOATE [J].
HARAMOTO, Y ;
KAWASHIMA, K ;
KAMOGAWA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (02) :431-434
[10]   NEW OPTICALLY-ACTIVE LIQUID-CRYSTAL COMPOUNDS - (+)-4-ALKOXYPHENYL 4-[5-(2-METHYLBUTYL)-1,3-OXATHIAN-2-YL]BENZOATES [J].
HARAMOTO, Y ;
KAMOGAWA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (11) :3063-3065