STRUCTURAL INVESTIGATION OF DIBENZYLTIN(IV) COMPLEXES OF CARBOHYDRATES

被引：19

作者：

BUZAS, N

PUJAR, MA

NAGY, L

VERTES, A

KUZMANN, E

MEHNER, H

机构：

[1] ATTILA JOZSEF UNIV, DEPT INORGAN & ANALYT CHEM, H-6701 SZEGED, HUNGARY

[2] EOTVOS LORAND UNIV, DEPT NUCL CHEM, BUDAPEST, HUNGARY

[3] BUNDESANSTALT MATFORSCH & PRUFUNG, BERLIN, GERMANY

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1995年 / 189卷 / 02期

关键词：

D O I：

10.1007/BF02042602

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Dibenzyltin(IV) complexes of carbohydrate derivatives were prepared and studied by Mossbauer and FTIR spectroscopy and by thermogravimetry. The Mossbauer studies indicated that the reaction between dibenzyltin(IV)-dichloride and sugar-type Ligands led to reaction products containing tin(IV)-oxide. beside the dibenzyltin(IV) sugar complex. These two type of species were shown to be in weak interaction. Comparison of the experimental quadrupole splitting values with those calculated on the basis of the partial quadrupole splitting concept revealed the steric arrangements of the coordination sphere of tin(IV) in the sugar complexes.

引用

收藏

页码：237 / 245

页数：9

相关论文

共 25 条

[1] ASSESSMENT OF DI-BUTYLTIN AND TRI-BUTYLTIN INTERACTION WITH SKELETAL-MUSCLE MEMBRANES [J].

ALI, AA ;

UPRETI, RK ;

KIDWAI, AM .

BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 1990, 44 (01) :29-38

[2] INTERACTION OF DIBUTYLTIN AND TRIBUTYLTIN CHLORIDE WITH HUMAN-ERYTHROCYTE MEMBRANE [J].

ALI, AA ;

UPRETI, RK ;

KIDWAI, AM .

TOXICOLOGY LETTERS, 1987, 38 (1-2) :13-18

[3]

Bancroft G. M., 1973, MOSSBAUER SPECTROSCO

[4] ADDITIVE MODEL FOR SN-119 MOSSBAUER QUADRUPOLE SPLITTING IN 5-COORDINATE ORGANOTIN(IV) COMPOUNDS [J].

BANCROFT, GM ;

KUMARDAS, VG ;

SHAM, TK ;

CLARK, MG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (07) :643-654

[5]

BARBIERI R, 1981, CAN J SPECTROSC, V26, P194

[6] COORDINATION-NUMBER, SYMMETRY OF THE COORDINATION SPHERE OF TIN(IV) AND OLIGOMERIZATION IN CARBOHYDRATE COMPLEXES OF DIBUTYLTIN(IV) [J].

BURGER, K ;

NAGY, L ;

BUZAS, N ;

VERTES, A ;

MEHNER, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (16) :2499-2504

[7] EQUILIBRIUM AND SPECTROSCOPIC STUDIES OF DIETHYLTIN(IV) COMPLEXES FORMED WITH CARBOHYDRATE-DERIVATIVES OF THIAZOLIDINE-4-CARBOXYLIC ACID [J].

BUZAS, N ;

GYURCSIK, B ;

NAGY, L ;

ZHANG, YX ;

KORECZ, L ;

BURGER, K .

INORGANICA CHIMICA ACTA, 1994, 218 (1-2) :65-71

[8] THE CRYSTAL-STRUCTURE OF METHYL 4,6-O-BENZYLIDENE-2,3-O-DIBUTYLSTANNYLENE-ALPHA-D-GLUCOPYRANOSIDE [J].

CAMERON, TS ;

BAKSHI, PK ;

THANGARASA, R ;

GRINDLEY, TB .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1992, 70 (06) :1623-1630

[9]

DAVID S, 1979, NOUV J CHIM, V3, P63

[10] STRUCTURE OF 2,2-DIBUTYL-1,3,2-DIOXASTANNOLANE IN THE SOLID-STATE [J].

DAVIES, AG ;

PRICE, AJ ;

DAWES, HM ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (02) :297-302