HECK-TYPE REACTIONS IN WATER

被引：192

作者：

JEFFERY, T

机构：

[1] Laboratoire de Chimie, l'Ecole Normale Supérieure associé au CNRS -, 75231 Paris Cédex 05, 24, Rue Lhomond

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)76825-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The presence of water is determining for the efficiency of quaternary ammonium salt (QX) in palladium-catalysed vinylation of organic halides using an alkali metal carbonate as the base, whether QX is a chloride, a bromide or a hydrogensulfate. The [Pd/M(2)CO(3)/QX] catalyst system can even be used for performing the reactions in neat water, without organic solvent.

引用

收藏

页码：3051 / 3054

页数：4

相关论文

共 15 条

[1] CONJUGATE ADDITION VS VINYLIC SUBSTITUTION IN PALLADIUM-CATALYZED REACTION OF ARYL HALIDES WITH BETA-SUBSTITUTED-ALPHA,BETA-ENONES AND BETA-SUBSTITUTED-ALPHA,BETA-ENALS [J].

AMORESE, A ;

ARCADI, A ;

BERNOCCHI, E ;

CACCHI, S ;

CERRINI, S ;

FEDELI, W ;

ORTAR, G .

TETRAHEDRON, 1989, 45 (03) :813-828

[2] BETA-VINYL-GAMMA-BUTYROLACTONES VIA THE PALLADIUM-CATALYZED REACTION OF VINYL TRIFLATES WITH Z-2-BUTEN-1,4-DIOL [J].

ARCADI, A ;

BERNOCCHI, E ;

CACCHI, S ;

MARINELLI, F .

TETRAHEDRON, 1991, 47 (08) :1525-1540

[3] THIN-LAYER PHASE-TRANSFER CATALYSIS IN THE REACTION OF ALKYL CHLORIDES AND SOLID FORMATE SALT [J].

ARRAD, O ;

SASSON, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) :185-189

[4] SYNTHESIS OF SUBSTITUTED CINNAMIC-ACIDS AND CINNAMONITRILES VIA PALLADIUM CATALYZED COUPLING REACTIONS OF ARYL HALIDES WITH ACRYLIC-ACID AND ACRYLONITRILE IN AQUEOUS-MEDIA [J].

BUMAGIN, NA ;

MORE, PG ;

BELETSKAYA, IP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (03) :397-401

[5]

CARLSTROM AS, 1989, SYNTHESIS-STUTTGART, P414

[6] PALLADIUM-CATALYZED ALKYLATIONS IN AQUEOUS-MEDIA [J].

CASALNUOVO, AL ;

CALABRESE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4324-4330

[7]

Dehmlow E. V., 1988, J CHEM RES S, P384

[8]

GENET JP, 1992, SYNLETT, P715

[9]

Heck R.F., 1991, COMPREHENSIVE ORGANI, V4, P833, DOI DOI 10.1016/B978-0-08-052349-1.00110-4

[10]

Heck R. F., 1985, PALLADIUM REAGENTS O