THERMAL-BEHAVIOR OF CARBOHYDRATES STUDIED BY HEAT-FLOW CALORIMETRY

被引:118
作者
RAEMY, A
SCHWEIZER, TF
机构
[1] Nestle Products Technical Assistance, Co, Research Dep, La Tour de Peilz,, Switz, Nestle Products Technical Assistance Co, Research Dep, La Tour de Peilz, Switz
来源
JOURNAL OF THERMAL ANALYSIS | 1983年 / 28卷 / 01期
关键词
ALCOHOLS - Thermal Effects - SUGAR - Thermal Effects;
D O I
10.1007/BF02105282
中图分类号
O414.1 [热力学];
学科分类号
摘要
The technique of heat flow calorimetry was used to study the thermal behavior of different carbohydrates between 20 degree C and 270 degree C. The samples were analyzed by heating in sealed cells. The temperature range in which exothermic reactions, due to thermal decomposition, occurred varied widely depending on the type of carbohydrate investigated. Reaction enthalpies of 44 sugars and polysaccharides are given. Endothermic phenomena, such as fusion or vaporization of crystallized water, were also observed: fusion temperatures and enthalpies of 34 sugars and sugar alcohols are listed. Calorimetric curves showing crystallization of amorphous sucrose, cellobiose and lactose are also presented.
引用
收藏
页码:95 / 108
页数:14
相关论文
共 45 条
[1]   COMPETITIVE REACTIONS IN THERMAL DECOMPOSITION OF CELLULOSE [J].
ARSENEAU, DF .
CANADIAN JOURNAL OF CHEMISTRY, 1971, 49 (04) :632-&
[2]  
Berlin E., 1971, Thermo-chim. Acta, V2, P143, DOI 10.1016/0040-6031(71)85043-8
[3]  
BURGER A, 1979, MIKROCHIM ACTA, V2, P273
[4]  
Burger A., 1982, PHARM UNSERER Z, V6, P177
[5]  
CHARSLEY EL, 1981, 2ND P EUR S THERM AN, P593
[6]  
Chevalley J., 1970, REV INT CHOCOLATE, V25, P3
[7]   THE PREPARATION AND EXAMINATION OF PARTIALLY COMBUSTED CELLULOSE CHARS [J].
DOLLIMORE, D ;
HOATH, JM .
THERMOCHIMICA ACTA, 1981, 45 (01) :103-113
[8]   THE APPLICATION OF THERMAL-ANALYSIS TO THE COMBUSTION OF CELLULOSE [J].
DOLLIMORE, D ;
HOATH, JM .
THERMOCHIMICA ACTA, 1981, 45 (01) :87-102
[9]  
Fassman G. D., 1975, HDB BIOCH MOL BIOL
[10]  
FERNANDEZMARTIN F, 1979, 8TH P EUR FOOD S FOO, P523