FACILE PREPARATION OF NI2(ETA-5-C5ME5)2(MU-CO)2

被引：10

作者：

BOAG, NM

GOODBY, AJ

QUYOUM, R

机构：

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 09期

关键词：

D O I：

10.1021/om00045a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of NiBr2.DME with C5Me5MgCl.THF at -30-degrees-C followed by sequential treatment with CO and amalgamated zinc at 0-degrees-C affords Ni2(eta-5-C5Me5)2(mu-CO)2 in reasonable yield. The compounds [Ni[eta-5-C5Me5)-(CO)]-M+ (M = Li, Na, PPN) have been synthesized and trapped with Ph3SnCl, forming Ni(eta-5-C5Me5)(CO)(SnPh3).

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页码：3135 / 3136

页数：2

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