QUATERNARY BORON .8. INTERFACIAL SUPERBASE CHEMISTRY - THE CATALYZED REACTION OF POTASSIUM HYDRIDE WITH TRISIAMYLBORANE - A NEW CONVENIENT SYNTHESIS OF POTASSIUM TRISIAMYLBOROHYDRIDE

被引：5

作者：

BROWN, CA ^{[1
]}

KRISHNAMURTHY, S ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1986年 / 51卷 / 02期

关键词：

D O I：

10.1021/jo00352a020

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：238 / 240

页数：3

共 18 条

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[2] QUATERNARY BORON .5. UNEXPECTED HYDRIDE TRANSFER-REACTION OF HYDRIDOBORATES - CONVENIENT NEW ROUTE TO HIGHLY HINDERED POTASSIUM TRIALKYLHYDRIDOBORATES [J].

BROWN, CA ;

HUBBARD, JL .

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[3] RAPID QUANTITATIVE REACTION OF POTASSIUM HYDRIDE WITH WEAK LEWIS ACIDS - HIGHLY CONVENIENT NEW ROUTE TO HINDERED COMPLEX BOROHYDRIDES [J].

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[4] FACILE REACTION OF POTASSIUM HYDRIDE WITH TRIALKYLBORANES, A CONVENIENT GENERAL SYNTHESIS OF SIMPLE AND HINDERED POTASSIUM TRIALKYLBOROHYDRIDES UNDER EXCEPTIONALLY MILD CONDITIONS [J].

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[5] POTASSIUM TRI-ISOPROPOXYBOROHYDRIDE - NEW MILD COMPLEX HYDRIDE REDUCING AGENT WITH HIGH STEREOSELECTIVITY FOR REDUCTION OF KETONES [J].

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KIM, SC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (12) :391-391

[6] POTASSIUM HYDRIDE, A HIGHLY ACTIVE NEW HYDRIDE REAGENT - REACTIVITY, APPLICATIONS, AND TECHNIQUES IN ORGANIC AND ORGANOMETALLIC REACTIONS [J].

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JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (26) :3913-3918

[7]

BROWN CA, 1974, SYNTHESIS-STUTTGART, P427

[8]

BROWN CA, 1977, INORG SYNTH, V17, P26

[9]

BROWN CA, 1979, 4TH INT M BOR SNOWB

[10] RATES OF REACTION OF SODIUM BOROHYDRIDE WITH SOME REPRESENTATIVE KETONES [J].

BROWN, HC ;

ICHIKAWA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (03) :373-&

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