EXPLOITING STERIC SHIELDING - TUNING TERPENOID-DERIVED OXAZOLIDIN-2-ONES AS CHIRAL AUXILIARIES FOR THE DIELS-ALDER REACTION

被引：19

作者：

BANKS, MR ^{[1
]}

BLAKE, AJ ^{[1
]}

BROWN, AR ^{[1
]}

CADOGAN, JIG ^{[1
]}

GAUR, S ^{[1
]}

GOSNEY, I ^{[1
]}

HODGSON, PKG ^{[1
]}

THORBURN, P ^{[1
]}

机构：

[1] BP INT LTD,CTR RES & ENGN,SUNBURY TW16 7LN,MIDDX,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 03期

关键词：

D O I：

10.1016/0040-4039(94)85088-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Preparative methodology is described for access to three different terpenoid-derived oxazolidin-2-ones 4, 8, and 11, of which the latter, obtained from camphene in four steps, provides virtually complete asymmetric induction when acting as a chiral auxiliary in Diels-Alder cycloaddition reactions with cyclopentadiene.

引用

页码：489 / 492

页数：4

共 11 条

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