CALORIMETRY OF POLY-(ACRYLIC ACID) ADSORPTION ON TIO2

被引：36

作者：

BOHMER, MR ^{[1
]}

SOFI, YE ^{[1
]}

FOISSY, A ^{[1
]}

机构：

[1] UFR SCI & TECH,ELECTROCHIM SOLIDES LAB,F-25030 BESANCON,FRANCE

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1994年 / 164卷 / 01期

关键词：

D O I：

10.1006/jcis.1994.1151

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of low molecular weight poly-(acrylic acid) (PAA) from aqueous solutions on TiO2 (anatase) has been studied and at pH 10 as a function of the electrolyte type and concentration. At low pH an exothermic heat of adsorption is found but at high pH in CaCl2 and NaCl solutions heat is consumed during adsorption. This endothermic effect is related to specific interactions between the cations and the TiO2 surface. If a Ca-salt is used the endothermic effect also originates from Ca2+ PAA interactions. The most likely driving force for PAA adsorption on TiO2 at high pH is the entropy gain by the release of hydration water of specifically interacting ions. (C) 1994 Academic Press, Inc.

引用

页码：126 / 135

页数：10

共 24 条

[1] ADSORPTION OF WEAK POLYELECTROLYTES ON HIGHLY CHARGED SURFACES - POLY(ACRYLIC ACID) ON POLYSTYRENE LATEX WITH STRONG CATIONIC GROUPS
BLAAKMEER, J
BOHMER, MR
STUART, MAC
FLEER, GJ
[J]. MACROMOLECULES, 1990, 23 (08) : 2301 - 2309
[2] SYNTHESIS OF A POLYSTYRENE LATEX WITH A POSITIVE, PH INDEPENDENT, SURFACE-CHARGE
BLAAKMEER, J
FLEER, GJ
[J]. COLLOIDS AND SURFACES, 1989, 36 (04): : 439 - 447
[3] WEAK POLYELECTROLYTES BETWEEN 2 SURFACES - ADSORPTION AND STABILIZATION
BOHMER, MR
EVERS, OA
SCHEUTJENS, JMHM
[J]. MACROMOLECULES, 1990, 23 (08) : 2288 - 2301
[4] Burgess J., 1978, METAL IONS SOLUTION
[5] THERMODYNAMICS OF PROTON CHARGE FORMATION ON OXIDES - MICROCALORIMETRY
DEKEIZER, A
FOKKINK, LGJ
LYKLEMA, J
[J]. COLLOIDS AND SURFACES, 1990, 49 (1-2): : 149 - 163
[6] DUPONT L, UNPUB
[7] ADSORPTION OF POLYACRYLIC-ACID ON TITANIUM-DIOXIDE
FOISSY, A
ATTAR, AE
LAMARCHE, JM
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 96 (01) : 275 - 287
[8] SURFACE AND DIFFUSE-LAYER CHARGE AT THE TIO2-ELECTROLYTE INTERFACE
FOISSY, A
MPANDOU, A
LAMARCHE, JM
JAFFREZICRENAULT, N
[J]. COLLOIDS AND SURFACES, 1982, 5 (04): : 363 - 368
[9] FOISSY A, THESIS U BESANCON FR
[10] FOKKINK LGJ, 1986, J ELECTROANAL CHEM, V329, P187

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