DYNAMICS OF PHASE-SEPARATION IN MESOMORPHIC MIXTURES

被引:17
作者
LANSAC, Y [1 ]
FRIED, F [1 ]
MAISSA, P [1 ]
机构
[1] INST NON LINEAIRE NICE,UMR 129,F-06560 VALBONNE,FRANCE
关键词
D O I
10.1080/02678299508036699
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We describe the dynamics of phase separation and transition processes, in binary mesomorphic mixtures with the help of a system of two coupled partial derivative equations. We emphasize, both analytically and numerically, that, depending on the regions of the phase diagram, the dynamical behaviour may result either from a two step process (first the phase transition, then the phase separation) or from a process showing salient features of the Cahn-Hilliard spinodal decomposition (bicontinuous periodic networks in the transient stages). The dynamics of evolution of the domain patterns are illustrated with the help of numerical simulations in which homeotropic and planar anchorages are visualized.
引用
收藏
页码:829 / 837
页数:9
相关论文
共 25 条
[1]   PHASE-BEHAVIOR OF POLYMER LIQUID-CRYSTAL BLENDS [J].
AHN, W ;
KIM, CY ;
KIM, H ;
KIM, SC .
MACROMOLECULES, 1992, 25 (19) :5002-5007
[2]  
[Anonymous], 1983, PHASE TRANSITIONS CR
[3]  
CAHN JW, 1968, T METALL SOC AIME, V242, P1966
[4]   OBSERVATION OF ANISOTROPIC DROPLETS IN NEMATIC-NEMATIC PHASE-SEPARATION [J].
CASAGRANDE, C ;
FABRE, P ;
GUEDEAU, MA ;
VEYSSIE, M .
EUROPHYSICS LETTERS, 1987, 3 (01) :73-78
[5]   ANISOTROPIC FEATURES IN THE DYNAMICS OF NEMATIC-NEMATIC PHASE-SEPARATION [J].
CASAGRANDE, C ;
VEYSSIE, M ;
KNOBLER, CM .
PHYSICAL REVIEW LETTERS, 1987, 58 (20) :2079-2082
[6]  
DEE G, 1980, PROG THEOR PHYS, V65, P365
[7]   SPINODAL DECOMPOSITION IN MIXTURES CONTAINING NEMATOGENS .2. KINETICS OF SPINODAL DECOMPOSITION [J].
DORGAN, JR .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (11) :9094-9106
[8]   ANISOTROPIC SPINODAL DECOMPOSITION [J].
ESSERY, RLH ;
BALL, RC .
EUROPHYSICS LETTERS, 1991, 16 (04) :379-384
[9]   STATISTICAL THERMODYNAMICS OF SEMI-FLEXIBLE CHAIN MOLECULES [J].
FLORY, PJ .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1956, 234 (1196) :60-73
[10]   PHASE EQUILIBRIA IN SOLUTIONS OF ROD-LIKE PARTICLES [J].
FLORY, PJ .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1956, 234 (1196) :73-89