SYNTHESIS AND MOLECULAR-STRUCTURES OF THE REDOX PAIR (OCTAETHYLPORPHINATO)BIS(PENTAMETHYLENE SULFIDE)OSMIUM(II) AND (OCTAETHYLPORPHINATO)BIS(PENTAMETHYLENE SULFIDE)OSMIUM(III) HEXAFLUOROPHOSPHATE

被引：6

作者：

SCHEIDT, WR ^{[1
]}

NASRI, H ^{[1
]}

机构：

[1] UNIV CTR MONASTIR,FAC SCI MONASTIR,DEPT CHIM,MONASTIR 5000,TUNISIA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 08期

关键词：

D O I：

10.1021/ic00112a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the preparation, crystallization, and molecular structures of the redox pair (octaethylporphinato)bis(pentamethylene sulfide)osmium(II) and (octaethylporphinato)bis(pentamethylene sulfide)osmium(III) hexafluorophosphate. Both complexes have the osmium atom centered in the porphyrin plane with required inversion symmetry. The average Os-II = N-p 2.050(9) Angstrom and the axial Os-II-S distance is 2.352(2) Angstrom. The average Os-III-N-p is possibly shorter, at 2.046(2) Angstrom, and the axial Os-III-S distance is longer, at 2.382(2) Angstrom. Crystal data for [Os(OEP)(PMS)(2)]: a = 10.540(6) Angstrom, b = 10.620(6) Angstrom, c = 11.001(4) Angstrom, alpha = 99.21(3)degrees, beta = 95.35(3)degrees, gamma = 117.41(3)degrees, triclinic, space group P (1) over bar, V = 1059.3 Angstrom(3), Z = 1, unique observed data = 4895, R(1) = 0.047, R(2) = 0.063. Crystal data for [Os(OEP)(PMS)(2)]PF6: a = 10.449(8) Angstrom, b = 11.161(7) Angstrom, c = 11.523(2) Angstrom, alpha = 98.04(3)degrees, beta = 104.63(2)degrees, gamma = 111.93(7)degrees, triclinic, space group P (1) over bar, V = 1164.4 Angstrom(3), Z = 1, unique observed data = 5390, R(1) = 0.036, R(2) = 0.047.

引用

页码：2190 / 2193

页数：4

共 26 条

[1] PORPHYRINS .36. SYNTHESIS AND OPTICAL AND ELECTRONIC PROPERTIES OF SOME RUTHENIUM AND OSMIUM OCTAETHYLPORPHYRINS [J].

ANTIPAS, A ;

BUCHLER, JW ;

GOUTERMAN, M ;

SMITH, PD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (10) :3015-3024

[2] OSMIUM THIOETHER CHEMISTRY - SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURES OF [OS([9]ANES3)2][PF6]2.2MENO2, [OS(4-MEC6H4PRI)([9]ANES3)][BPH4]2.MENO2 AND [OSH(CO)(PPH3)([9]ANES3)]PF6.0.5CH2CL2 ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) [J].

BELL, MN ;

BLAKE, AJ ;

CHRISTIE, RM ;

GOULD, RO ;

HOLDER, AJ ;

HYDE, TI ;

SCHRODER, M ;

YELLOWLEES, LJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (20) :2977-2986

[3] OSMOCHROMES (OSMIUM ANALOGS OF HEMOCHROMES) - PROOF OF SUPEROXIDE AND HYDROPEROXIDE GENERATION FROM DIOXYGEN AND A METALLOPORPHYRIN LACKING A FREE COORDINATION SITE [J].

BILLECKE, J ;

KOKISCH, W ;

BUCHLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (10) :3622-3624

[4] METAL-COMPLEXES WITH TETRAPYRROLE LIGANDS .30. THE MANGANESE NITROGEN TRIPLE BOND - SYNTHESIS AND MOLECULAR STEREOCHEMISTRY OF (5,15-DIMETHYL-2,3,7,8,12,13,17,18-OCTAETHYL-5H,15H-PORPHINATO)NITRIDOMANGANESE(V) [J].

BUCHLER, JW ;

DREHER, C ;

LAY, KL ;

LEE, YJA ;

SCHEIDT, WR .

INORGANIC CHEMISTRY, 1983, 22 (06) :888-891

[5] METAL-COMPLEXES WITH TETRAPYRROLE LIGANDS .15. CARBONYLOSMIUM PORPHODIMETHENE - SYNTHESIS, AND DETERMINATION OF CRYSTAL AND MOLECULAR-STRUCTURE [J].

BUCHLER, JW ;

LAMLAY, K ;

SMITH, PD ;

SCHEIDT, WR ;

RUPPRECHT, GA ;

KENNY, JE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 110 (01) :109-120

[6] THE X-RAY MOLECULAR-STRUCTURE OF (ETA-6-PARA-CYMENE)-(DIMETHYLSULFOXIDE-S)DICHLOROOSMIUM(II) [J].

CABEZA, JA ;

ADAMS, H ;

SMITH, AJ .

INORGANICA CHIMICA ACTA, 1986, 114 (02) :L17-L18

[7] SYNTHESIS, REACTIVITY, AND X-RAY STRUCTURAL CHARACTERIZATION OF TRANS-DIOXOOSMIUM(VI) PORPHYRIN COMPLEXES [J].

CHE, CM ;

CHUNG, WC ;

LAI, TF .

INORGANIC CHEMISTRY, 1988, 27 (16) :2801-2804

[8] TRIPHENYLPHOSPHINE REDUCTION OF DIOXOOSMIUM(VI) PORPHYRINS - CRYSTAL-STRUCTURES OF BIS(TRIPHENYLPHOSPHINE OXIDE)(OCTAETHYLPORPHINATO)OSMIUM(II) AND BIS(TRIPHENYLPHOSPHINE)(MESO-TETRAPHENYLPORPHINATO)OSMIUM(II) [J].

CHE, CM ;

LAI, TF ;

CHUNG, WC ;

SCHAEFER, WP ;

GRAY, HB .

INORGANIC CHEMISTRY, 1987, 26 (23) :3907-3911

[9] DIALKOXYOSMIUM(IV) PORPHYRINS - CRYSTAL AND MOLECULAR-STRUCTURES OF IETHOXY, DIPHENOXY, AND BIS(2-PROPANOLATO) (MESO-TETRAPHENYLPORPHYRINATO)OSMIUM(IV) [J].

CHE, CM ;

HUANG, JS ;

LI, ZY ;

POON, CK ;

TONG, WF ;

LAI, TF ;

CHENG, MC ;

WANG, CC ;

WANG, Y .

INORGANIC CHEMISTRY, 1992, 31 (25) :5220-5225

[10] MERCAPTIDE COMPLEXES OF OSMIUM PORPHYRINS - STRUCTURE OF OS(TTP)(SC6F4H)2 [J].

COLLMAN, JP ;

BOHLE, DS ;

POWELL, AK .

INORGANIC CHEMISTRY, 1993, 32 (19) :4004-4011

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