THE STRUCTURE OF FLUORENE (C13H10) AND THE FLUORENE ARGON VANDERWAALS COMPLEX FROM A HIGH-RESOLUTION NEAR ULTRAVIOLET-SPECTRUM

被引：52

作者：

MEERTS, WL

MAJEWSKI, WA

VANHERPEN, WM

机构：

[1] Katholieke Univ, Fysisch Lab,, Nijmegen, Neth, Katholieke Univ, Fysisch Lab, Nijmegen, Neth

来源：

CANADIAN JOURNAL OF PHYSICS | 1984年 / 62卷 / 12期

关键词：

ARGON - Spectroscopic Analysis - SPECTROSCOPY; ULTRAVIOLET; -; Applications;

D O I：

10.1139/p84-175

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The high-resolution fluorescence excitation spectrum of the fluorene molecule and its van der Waals complex with argon has been studied. Rotationally resolved spectra were obtained by combining a well-collimated supersonic molecular beam with a single frequency tunable ultraviolet (uv) source. The S//1 implied by S//0O//0**0 vibronic transitions in fluorene and fluorene-argon were observed. The rotational constants of both molecules were determined and from these the structure of the fluorene-argon complex has been deduced. The argon atom is located above the middle five-membered ring.

引用

页码：1293 / 1299

页数：7

共 18 条

[1] SPECTROSCOPY OF THE FLUORENE MOLECULE IN PLANAR SUPERSONIC EXPANSIONS [J].