EPR OF BEDT-TTF SALTS CONTAINING MAGNETIC ANIONS, CUIIX4(2-), X = CL OR BR

被引：7

作者：

KURMOO, M ^{[1
]}

KANAZAWA, D ^{[1
]}

DAY, P ^{[1
]}

机构：

[1] INST LAUE LANGEVIN,F-33042 GRENOBLE,FRANCE

来源：

SYNTHETIC METALS | 1991年 / 42卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(91)92031-C

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The EPR of BEDT-TTF salts containing Cu(II)X4(2-), mixed valent [Cu(II)X4(2-) / Cu(I)X2-] and Cu(I)Cl2- are reported. The EPR signals originate from the Cu(II)X4(2-) (d9) ions in the semiconducting salt and from both the Cu moment and the conduction electrons in the highly conducting salt. In the mixed valent salts, only one signal is observed, which is associated with strong interaction between the localised moments on the Cu atoms and the unpaired moments on the organic moiety.

引用

页码：2123 / 2126

页数：4

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