VIBRATION-TO-VIBRATION ENERGY TRANSFER IN GAS MIXTURES CONTAINING NITROUS OXIDE

被引：85

作者：

YARDLEY, JT

机构：

[1] Department of Chemistry and Chemical Engineering, University of Illinois, Urbana, IL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 49卷 / 06期

关键词：

D O I：

10.1063/1.1670489

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fluorescence from the asymmetric stretching vibration (Δ v3=1) of N2O is observed following excitation by a Q-switched N2O laser. The time dependence of the fluorescence is used to measure the rates of relaxation of N2O(00°1) at 25°C as the result of intermolecular collisions with N2O, He, Ne, Ar, Kr, H2, and D2. The rate of energy exchange between N 2O(00°1) and N2(v=1) is also determined.

引用

页码：2816 / &

共 21 条

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