A NEW APPROACH TO REMOTE ASYMMETRIC INDUCTION IN THE DIASTEREOSELECTIVE REDUCTION OF GAMMA-KETO ESTERS BY USE OF A CHIRAL PODAND AS CHIRAL AUXILIARY

被引：29

作者：

TAMAI, Y

KOIKE, S

OGURA, A

MIYANO, S

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000799

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient 1,7-asymmetric induction was achieved with up to 82% diastereoisomeric excess (d.e.) in the diastereoselective reduction of the gamma-keto ester 4 and omicron-acetylbenzoate 6 using the chiral podand 2 as chiral auxiliary.

引用

页码：799 / 800

页数：2

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