DOMAIN-LATTICE ORDERING IN MICROPHASE-SEPARATED COPOLYMERS

被引:1
作者
OHTA, T [1 ]
IWAI, Y [1 ]
ITO, A [1 ]
GUNTON, JD [1 ]
机构
[1] KENYON COLL,DEPT PHYS,GAMBIER,OH 43022
来源
PHYSICA B | 1995年 / 213卷
基金
美国国家科学基金会;
关键词
D O I
10.1016/0921-4526(95)00246-6
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We carry out computer simulations of domain growth in a microphase separation of block copolymers in two dimensions. After a quench of the system to below the phase-separation temperature, disk-shaped domains emerge, grow and tend to constitute a hexagonal lattice. However, the ordering is not completely global, in that there are many grain boundaries. We have found that there is a strong correlation between the lattice disordering and the droplet-size distribution. The domain patterns that form from a heterogeneous initial condition are also discussed.
引用
收藏
页码:672 / 675
页数:4
相关论文
共 11 条
[1]   PHASE-TRANSITIONS IN LANGMUIR MONOLAYERS OF POLAR-MOLECULES [J].
ANDELMAN, D ;
BROCHARD, F ;
JOANNY, JF .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (06) :3673-3681
[2]  
[Anonymous], 1983, PHASE TRANSIT CRIT P
[3]   CELL DYNAMIC SYSTEM APPROACH TO BLOCK COPOLYMERS [J].
BAHIANA, M ;
OONO, Y .
PHYSICAL REVIEW A, 1990, 41 (12) :6763-6771
[4]   BLOCK COPOLYMER THERMODYNAMICS - THEORY AND EXPERIMENT [J].
BATES, FS ;
FREDRICKSON, GH .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1990, 41 (01) :525-557
[5]   CONCENTRIC PATTERNS IN MESOSCOPIC SPINODAL DECOMPOSITION [J].
FURUKAWA, H .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1994, 63 (10) :3744-3750
[6]   PHASE-TRANSITIONS WITH SPONTANEOUS MODULATION THE DIPOLAR ISING FERROMAGNET [J].
GAREL, T ;
DONIACH, S .
PHYSICAL REVIEW B, 1982, 26 (01) :325-329
[7]  
GARRIDO L, 1992, LECTURE NOTE PHYSICS, V415
[8]  
KOIZUMI S, 1994, MACROMOLECULES, V26, P6532
[9]   EQUILIBRIUM MORPHOLOGY OF BLOCK COPOLYMER MELTS [J].
OHTA, T ;
KAWASAKI, K .
MACROMOLECULES, 1986, 19 (10) :2621-2632
[10]  
SEUL M, 1994, J PHYS I, V4, P319, DOI 10.1051/jp1:1994140