PD(O) CATALYZED HYDROSTANNATION OF CONJUGATED DIENES - A FACILE AND HIGHLY REGIOSELECTIVE AND STEREOSELECTIVE SYNTHESIS OF (Z)-2-ALKENYLSTANNANES

被引:23
作者
MIYAKE, H
YAMAMURA, K
机构
关键词
D O I
10.1246/cl.1992.507
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetrakis(triphenylphosphine)palladium(0) catalyzes the hydrostannation of conjugated dienes. The reaction proceeds highly regio- and stereoselectively to give (Z)-2-alkenyltributylstannanes. This method is convenient for the stereoselective synthesis of allyltin compounds.
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页码:507 / 508
页数:2
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