THE SYNTHESIS OF ALPHA-STANNYL-SILANES AND THEIR USE IN THE FORMATION OF ALKENES

被引：14

作者：

BARRETT, AGM

HILL, JM

机构：

[1] Department of Chemistry, Colorado State University Fort Collins

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 28期

基金：

美国国家科学基金会;

关键词：

PETERSON REACTION; ORGANOSILICON COMPOUNDS; REAGENTS; OXYGEN;

D O I：

10.1016/S0040-4039(00)92687-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Stannyl-silanes were prepared from aldehydes via alpha-hydroxy- and alpha-chloro-silanes. Stannyl-silane 5d was transmetallated using non-butylithium and the resultant alpha-lithio-silane condensed with aldehydes to yield alkenes.

引用

页码：3285 / 3288

页数：4

共 23 条

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