ZIRCONIUM MEDIATED OR CATALYZED HIGHLY STEREOSELECTIVE CYCLIZATION OF 1,4,7-TRIENES

被引：24

作者：

TAKAHASHI, T ^{[1
]}

KOTORA, M ^{[1
]}

KASAI, K ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 23期

关键词：

D O I：

10.1039/c39940002693

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclization of 1,4,7-trienes, which are easily prepared by double allylation reaction of alkynes, proceeded in the presence of a stoichiometric or catalytic amount of zirconocene compounds to give only cis isomers (>98% stereoselectivity).

引用

页码：2693 / 2694

页数：2

共 17 条

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