STRUCTURE DETERMINATION OF A NICKEL CROCONATE COMPLEX - [NI(OH2)(C5O5)(C3H4N2)3]H2O

被引：20

作者：

DEGUENON, D ^{[1
]}

CASTAN, P ^{[1
]}

DAHAN, F ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S010827019000823X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aqua(4,5-dihydroxy-4-cyclopentene-1,2,3-trionato)tris(imidazole)?? nickel(II) monohydrate, C14H14N6NiO6.H2O, M(r) = 439.0, monoclinic, P2(1)/c, a = 8.581 (1), b = 9.442 (1), c = 22.583 (2) angstrom, beta = 93.06 (1)-degrees, V = 1827.1 (7) angstrom 3, Z = 4, D(x) = 1.596 Mg m-3, lambda-(Mo K-alpha) = 0.71073 angstrom, mu = 1.11 mm-1, F(000) = 904, T = 293 K. Full-matrix least-squares refinement based on 2761 reflections led to R and wR values of 0.034 and 0.037 respectively. The coordination of the metal is ensured by three imidazole groups, one water molecule and one croconate molecule acting as chelating ligand.

引用

页码：433 / 435

页数：3

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