AMPHIPHILIC DYES FOR NONLINEAR OPTICS - DEPENDENCE OF 2ND HARMONIC-GENERATION ON FUNCTIONAL-GROUP SUBSTITUTION

被引:59
作者
BUBECK, C
LASCHEWSKY, A
LUPO, D
NEHER, D
OTTENBREIT, P
PAULUS, W
PRASS, W
RINGSDORF, H
WEGNER, G
机构
[1] HOECHST AG,W-3230 FRANKFURT 80,GERMANY
[2] MAX PLANCK INST POLYMER RES,W-6500 MAINZ,GERMANY
[3] UNIV MAINZ,INST ORGAN CHEM,W-6500 MAINZ,GERMANY
关键词
D O I
10.1002/adma.19910030111
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: Orientation of chromophores by using the Langmuir‐Blodgett film‐prepration procedure, to a degree practically impossible to achieve by poling in polymer matrices in an electric field, has held to materials exhibiting the highest values of the second order susceptibility (χ2) yet known. The effect of different functional groups in both phenylhydrazone and stryrylpyridinium compounds on both molecular nonlinearity and order in the films the factors which most strongly influence (χ2) has been investigated and a thioether substituent is found to increas (χ2) significantly. Copyright © 1991 Verlag GmbH & Co. KGaA, Weinheim
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页码:54 / 58
页数:5
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