HYDROFORMYLATION OF OCT-1-ENE WITH EXTREMELY HIGH-RATES USING RHODIUM CATALYSTS CONTAINING BULKY PHOSPHITES

被引：80

作者：

VANROOY, A ^{[1
]}

ORIJ, EN ^{[1
]}

KAMER, PCJ ^{[1
]}

VANDENAARDWEG, F ^{[1
]}

VANLEEUWEN, PWNM ^{[1
]}

机构：

[1] UNIV AMSTERDAM,DEPT CHEM ENGN,NIEUWE ACHTERGRACHT 166,1018 WV AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/c39910001096

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhodium complex containing tris(o-tert-butyl-p-methylphenyl) phosphite as a ligand catalyses the hydroformylation of oct-1-ene with good selectivity and extremely high rates; the rate constant, which is pseudo first-order in [H-2] and 1/[CO], shows that the reaction of hydrogen is the rate determining step.

引用

页码：1096 / 1097

页数：2

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