ROTATIONAL RELAXATION MEASUREMENTS IN OZONE - TEMPERATURE AND COLLISION PARTNER EFFECTS

被引：15

作者：

FLANNERY, CC

STEINFELD, JI

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 96卷 / 11期

关键词：

D O I：

10.1063/1.462319

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Time resolved infrared double resonance experiments have been conducted on ozone mixtures in order to determine rotational relaxation rates. A pulsed CO2 laser pumps a nu(3) <-- ground state transition, while a diode laser is tuned to a hot band transition so that the relaxation process in upsilon(3) = 1 may be observed. Nitrogen, oxygen, rare gas, and self-relaxation rates have been measured, and the temperature dependence of these rates has been investigated over the 200-300 K range.

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页码：8157 / 8163

页数：7

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