REDUCTIVE AND OXIDATIVE REACTIONS OF CALIX[4]ARENE DERIVATIVES

被引:17
作者
GRYNSZPAN, F [1 ]
DINOOR, N [1 ]
BIALI, SE [1 ]
机构
[1] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,IL-91904 JERUSALEM,ISRAEL
关键词
D O I
10.1016/S0040-4039(00)85995-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reductive cleavage of 25,26,27,28-tetramethoxy-p-tert-butylcalix[4]arene with K results in the formation of 26,28-dimethoxy-p-t-butylcalix[4]arene. The reaction of 25,27-dihydroxycalix[4]arene with NO2BF4 in acetonitrile results in its oxidation to calixdiquinone 6.
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页码:1909 / 1912
页数:4
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