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STRUCTURE AND PHYSICAL-PROPERTIES OF IODINE-DOPED FULLERENES

被引：14
作者：
KOBAYASHI, M
AKAHAMA, Y
KAWAMURA, H
SHINOHARA, H
SATO, H
SAITO, Y
机构：
[1] MIE UNIV,DEPT CHEM MAT,TSU,MIE 514,JAPAN
[2] MIE UNIV,DEPT ELECT ENGN,TSU,MIE 514,JAPAN
来源：
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 1993年 / 19卷 / 1-2期
关键词：
D O I：
10.1016/0921-5107(93)90172-J
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The crystal structure in C60Ix and C70Ix has been studied using X-ray diffraction measurement as a function of the reaction temperature. C60I2 has a base-centered orthorhombic structure. The electrical resistance measurement under high pressure showed that it had a semiconducting behavior with a gap of 0.3 eV at around room temperature. C70Ix has two different structures, depending on the iodine concentration: a body-centered tetragonal structure for x nearly equal to two and an unknown structure for x nearly equal to four. This structure is tentatively assigned as being a body-centered tetragonal structure. These compounds were not superconducting down to 1.3 K, as was checked using a.c. magnetic susceptibility measurements.
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页码：100 / 104
页数：5
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