STRUCTURE AND OPTICAL-PROPERTIES OF THERMOCHROMIC SCHIFF-BASES - CHARGE-TRANSFER INTERACTION AND PROTON-TRANSFER IN THE N-TETRACHLOROSALICYLIDENEANILINE AND N-TETRACHLOROSALICYLIDENE-1-PYRENYLAMINE CRYSTALS

被引：65

作者：

INABE, T ^{[1
]}

GAUTIERLUNEAU, I ^{[1
]}

HOSHINO, N ^{[1
]}

OKANIWA, K ^{[1
]}

OKAMOTO, H ^{[1
]}

MITANI, T ^{[1
]}

NAGASHIMA, U ^{[1
]}

MARUYAMA, Y ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES, INST MOLEC SCI, OKAZAKI 444, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 03期

关键词：

D O I：

10.1246/bcsj.64.801

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two kinds of N-salicylideneaniline derivatives, N-tetrachlorosalicylideneaniline (CL4SA) and N-tetrachlorosalicylidene-1-pyrenylamine (CL4SPY), have been prepared and subjected to structural and optical studies in the crystalline state. A thermochromic-type behavior of the former crystal has been observed as a shift of the absorption edge, while that of the latter crystal is much less pronounced. Fairly short O-H...N hydrogen bonds have been found in both compounds through crystallographic studies, which may be mainly due to a steric effect of chlorine substituents. The difference in the proton transfer behavior of CL4SA and CL4SPY should presumably be caused by an intermolecular charge-transfer interaction in the latter crystal.

引用

页码：801 / 810

页数：10

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