CATALYST AND SOLVENT EFFECTS ON THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE

被引：12

作者：

JENNER, G

机构：

[1] Laboratoire de Piézochimie Organique, Chimie Organique Appliquée (URA CNRS 469) EHICS, Université Louis Pasteur

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)97496-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl formate can be catalytically converted to acetic acid in the presence of transition metal compounds under carbon monoxide pressure. The nature of the metal catalyst, the promoter and the solvent are determining. Palladium and cobalt compounds associated with lithium iodide are the most efficient catalysts provided that the reaction is carried out in N-methylpyrrolidone under an adequate CO pressure. © 1990.

引用

页码：3887 / 3890

页数：4

共 8 条

[1]

DRURY DJ, 1984, ASPECTS HOMOGENEOUS, P206

[2]

Isogai N., 1974, [No title captured], Patent No. [US3839428A, 3839428]

[3] ACTIVITY OF RUTHENIUM IODINE CATALYSTS FOR THE CARBONYLATION OF ESTERS TO GIVE CARBOXYLIC-ACIDS [J].

LUTGENDORF, M ;

ELVEVOLL, EO ;

ROPER, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 289 (01) :97-106

[4] REACTIONS OF FORMIC-ACID .1. THE IRIDIUM-CATALYZED SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE [J].

PRUETT, RL ;

KACMARCIK, RT .

ORGANOMETALLICS, 1982, 1 (12) :1693-1699

[5]

ROPER M, 1985, ERDOL KOHLE ERDGAS P, V38, P38

[6]

ROPER M, 1984, ERDOL KOHLE ERDGAS P, V37, P506

[7] A HIGHLY EFFICIENT CATALYST SYSTEM FOR THE ISOMERIZATION OF METHYL FORMATE TO ACETIC-ACID [J].

SCHRECK, DJ ;

BUSBY, DC ;

WEGMAN, RW .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 47 (01) :117-121

[8] RHODIUM-CATALYZED REDUCTIVE CARBONYLATION OF METHYL FORMATE TO ACETALDEHYDE [J].

VANHOYE, D ;

MELLOUL, S ;

CASTANET, Y ;

MORTREUX, A ;

PETIT, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05) :683-684

← 1 →