THE CONDUCTIVITY OF DILUTE ELECTROLYTE-SOLUTIONS - EXPANDED LEE AND WHEATON EQUATION FOR SYMMETRICAL, UNSYMMETRICAL AND MIXED ELECTROLYTES

被引:13
作者
BIANCHI, H
FERNANDEZPRINI, R
机构
[1] Departamento Química de Reactores, Conisión Nacional de Energía Atómica, Capital Federal, 1429
关键词
ELECTROLYTIC CONDUCTIVITY; ELECTROLYTE MIXTURES; UNSYMMETRICAL ELECTROLYTES; LEE-WHEATON EQUATION;
D O I
10.1007/BF00646931
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The conductivity equation of Lee and Wheaton is expanded in a power series in the ionic strength I. Different levels of approximation are analyzed and it is shown that for unsymmetrical electrolytes it is necessary to keep the terms I3/2lnI and I2 to maintain the performance of the full equation.
引用
收藏
页码:557 / 570
页数:14
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