CHEMISTRY OF ORTHO-XYLIDENE METAL-COMPLEXES .4. STEREOSPECIFIC SYNTHESIS OF THE EARLY TRANSITION-METAL MESO-METALLACYCLES [M(CH(SIME3)C6H4CHSIME3-O)(ETA-C5H5)2] (M = TI, ZR, HF, OR NB), THEIR REVERSIBLE ONE-ELECTRON REDUCTION (M = TI, ZR, HF, OR NB) AND OXIDATION (M = NB) - AND THE X-RAY CRYSTAL-STRUCTURE OF THE ZIRCONIUM COMPLEX

被引：32

作者：

LAPPERT, MF ^{[1
]}

RASTON, CL ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1984年 / 05期

关键词：

D O I：

10.1039/dt9840000893

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：893 / 902

页数：10

共 44 条

[1] REVERSIBLE DOUBLE DEPROTONATION OF HEXAMETHYLBENZENE ON RUTHENIUM - FORMATION OF A FLUXIONAL ETA-3-BENZYL COMPOUND BY PROTONATION OF AN ORTHO-QUINODIMETHANE COMPLEX OF RUTHENIUM(0) [J].

BENNETT, MA ;

MCMAHON, JJ ;

TURNEY, TW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (05) :379-379

[2] CHEMISTRY OF ORTHO-XYLIDINE METAL-COMPLEXES .2. PREPARATION AND PROPERTIES OF THE ORTHO-XYLIDINE, METAL(IV) COMPLEXES - [M(CH2C6H4CH2-O) (ETA-C5H4R)2] (M = TI, ZR, HF, OR NB, R = H OR SIME3) AND [(M'(CH2C6H4CH2-O)2(OC4H8))N] (M' = TI, ZR, OR HF) - X-RAY CRYSTAL-STRUCTURES OF THE METALLAINDANES [M(CH2C6H4CH2-O)-(ETA-C5H4R)2] (R = H, M = TI, ZR, OR HF, R = SIME3, M = NB)CH [J].

BRISTOW, GS ;

LAPPERT, MF ;

MARTIN, TR ;

ATWOOD, JL ;

HUNTER, WF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (03) :399-413

[3]

CARDIN DJ, 1982, COMPREHENSIVE ORGANO, V3, P609

[4] ELECTROSYNTHESIS OF ALKYL AND ARYLOXY TITANIUM(III) COMPLEXES - ELECTROCHEMICAL AND SPECTROSCOPIC CHARACTERIZATION [J].

CHALOYARD, A ;

DORMOND, A ;

TIROUFLET, J ;

MURR, NE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (05) :214-216

[5] PREPARATION OF ETA-2-ETA-2-O-XYLYLENE COMPLEXES OF RUTHENIUM(O) VIA FACILE DELTA-HYDROGEN ABSTRACTION REACTIONS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [RU(CH2C6H4CH2)(PME2PH)3] [J].

CHAPPELL, SD ;

COLEHAMILTON, DJ ;

GALAS, AMR ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (09) :1867-1871

[6] FACILE DELTA-HYDROGEN ABSTRACTION FROM A RUTHENIUM COMPLEX - POSSIBLE 1 4-ETA-BONDING OF THE ORTHO-XYLYLENE LIGAND [J].

CHAPPELL, SD ;

COLEHAMILTON, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (07) :319-320

[7]

COTTON FA, 1980, ADV INORG CHEM, P822

[8] METAL SIGMA-HYDROCARBYLS, MR NORMAL-STOICHIOMETRY, STRUCTURES, STABILITIES, AND THERMAL-DECOMPOSITION PATHWAYS [J].

DAVIDSON, PJ ;

LAPPERT, MF ;

PEARCE, R .

CHEMICAL REVIEWS, 1976, 76 (02) :219-242

[9]

DAVIES GR, 1971, CHEM COMMUN, P677

[10]

Duff A. I., UNPUB

← 1 2 3 4 5 →