A SINGLE-CRYSTAL FOURIER-TRANSFORM RAMAN-SPECTROSCOPIC STUDY OF [CR3O(OOCCH3)6(H2O)3]CL.5H2O

被引：11

作者：

BOURKE, JP ^{[1
]}

CANNON, RD ^{[1
]}

GRINTER, R ^{[1
]}

JAYASOORIYA, UA ^{[1
]}

机构：

[1] UNIV E ANGLIA, SCH CHEM SCI, NORWICH NR4 7TJ, NORFOLK, ENGLAND

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1993年 / 49卷 / 5-6期

关键词：

D O I：

10.1016/0584-8539(93)80091-N

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Solution and single-crystal FT-Raman spectroscopy with polarization analysis have been used to assign a frequency of 147 cm-1 to the totally symmetric Cr3O stretching vibration of the complex cation in the dark coloured compound [Cr3O(OOCCH3)6(H2O)3]Cl.5H2O. For this vibration, the polarizability derivatives parallel to the metal triangle are shown to be greater in magnitude than that perpendicular to the triangle.

引用

页码：685 / 690

页数：6

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