A CONVENIENT SYNTHESIS OF BETA,GAMMA-UNSATURATED KETONES VIA ALLYLATION OF Z-1-HALO-1-ALKENYL-1,3,2-DIOXABOROLANE

被引：20

作者：

BROWN, HC

SOUNDARARAJAN, R

机构：

[1] H.C. Brown and R.B. Wetherill Laboratories of Chemistry, Purdue University, West Lafayette

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 38期

关键词：

D O I：

10.1016/0040-4039(94)88199-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient, general synthesis of beta,gamma-unsaturated ketones via allylation of Z-1-halo-1-alkenyl-1,3,2-dioxaborolane has been developed. The reactivity under different conditions and the effect of an additive, HMPA, is elucidated. A representative procedure for the synthesis of 1-nonen-3-one is described.

引用

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页码：6963 / 6966

页数：4

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