TIME-RESOLVED FLUORESCENCE SPECTROSCOPY OF MATRIX-ISOLATED SILVER ATOMS AFTER PULSED EXCITATION OF INNER-SHELL TRANSITIONS

被引：8

作者：

HEBERT, T ^{[1
]}

WIGGENHAUSER, H ^{[1
]}

SCHRIEVER, U ^{[1
]}

KOLB, DM ^{[1
]}

机构：

[1] MAX PLANCK GESELL,FRITZ HABER INST,FARADAYWEG 4-6,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 92卷 / 03期

关键词：

D O I：

10.1063/1.458089

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The energy dissipation in matrix-isolated silver atoms after pulsed vacuum ultraviolet (VUV) excitation of 4d-5p transitions has been studied by time-resolved fluorescence spectroscopy. The decay behavior of the various fluorescence bands has been analyzed and a model for the relaxation process proposed within the framework of a two-dimensional configuration-coordinate diagram. If minute quantities of Ag2 are present in the matrix, the analysis requires consideration of energy transfer between silver atoms and dimers. © 1990 American Institute of Physics.

引用

页码：1575 / 1580

页数：6

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