ELECTROLUMINESCENCE

被引：21

作者：

VELASCO, JG

机构：

[1] School of Sciences, Department of Chemistry, Autonomous University of Madrid, Madrid

来源：

ELECTROANALYSIS | 1991年 / 3卷 / 4-5期

关键词：

D O I：

10.1002/elan.1140030405

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A definition of electrogenerated luminescence (ECL) is given. Chemiluminescent reactions of different kinds are cited, as well as various types of pathway to the formation of the emitting excited state. After a consideration of the energetic and kinetic requirements for ECL-producing reactions, the experimental conditions are examined. The important concept of ECL efficiency is introduced, as well as the feasibility of elucidating the mechanisms of ECL reactions. Some interesting new ECL systems are mentioned, together with examples of analytical applications of such schemes.

引用

页码：261 / 271

页数：11

共 69 条

[1]

BARD AJ, 1973, CHEMILUMINESCENCE BI, P193

[2]

BARD AJ, 1975, EXCIPLEX, P305

[3] ESTIMATION OF EXCITED-STATE REDOX POTENTIALS BY ELECTRON-TRANSFER QUENCHING - APPLICATION OF ELECTRON-TRANSFER THEORY TO EXCITED-STATE REDOX PROCESSES [J].