CARRIER-MEDIATED TRANSPORT OF PLATINUM(IV) THROUGH A SUPPORTED LIQUID MEMBRANE IMPREGNATING AN 8-QUINOLINOL DERIVATIVE

被引：11

作者：

FU, JS ^{[1
]}

NAKAMURA, S ^{[1
]}

AKIBA, K ^{[1
]}

机构：

[1] TOHOKU UNIV,INST ADV MAT PROC,SENDAI,MIYAGI 98077,JAPAN

来源：

JOURNAL OF MEMBRANE SCIENCE | 1995年 / 105卷 / 03期

关键词：

SUPPORTED LIQUID MEMBRANE; LIQUID-LIQUID EXTRACTION; CARRIER-MEDIATED TRANSPORT; 8-QUINOLINOL DERIVATIVE; PLATINUM(IV);

D O I：

10.1016/0376-7388(95)00069-O

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The transport behavior of Pt(IV) has been studied through a supported liquid membrane (SLM) containing a long-chain 8-quinolinol, LIX 26, as a mobile carrier. Platinum(IV) was extracted with LIX 26 from an HCl solution via an anion exchange reaction and stripped from the loaded organic phase by a weakly acidic solution (pH > 1). Platinum (IV) was nearly quantitatively transported across an SLM impregnating 15% (v/v) LIX 26 and 10% (v/v) 1-octanol in kerosene from a feed solution of 1-2 M HCl into a weakly acidic product solution. The transport rate of Pt(IV) was related to the distribution ratio on the feed side. Platinum(IV) was efficiently enriched in the product solution with high recovery.

引用

页码：281 / 286

页数：6

共 12 条

[1] TRANSPORT OF URANIUM(VI) THROUGH A SUPPORTED LIQUID MEMBRANE CONTAINING LIX-63 [J].