STRUCTURE OF A BETA-CYCLODEXTRIN VANILLIN INCLUSION COMPLEX

被引：27

作者：

DIVAKAR, S

机构：

[1] Organic Chemistry Section, Food Chemistry Department, Central Food Technological Research Institute

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1990年 / 38卷 / 04期

关键词：

D O I：

10.1021/jf00094a005

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

Vanillin was found to form a stable complex with β-cyclodextrin. A binding constant value of 1.11 X 104M-1was determined for the 1:1 complex.-1H NMR chemical shift differences and circular dichroism spectra indicated that both phenolic end and aldehyde end were affected by complexation. 2D nuclear Overhauser enhancement spectroscopy indicated proximity of OCH3 in vanillin to the anomeric protons of β -cyclodextrin. 1D difference NOE experiments have revealed that vanillin exists with the phenolic end nearer to the narrower end and the aldehyde end to the wider end of the torusshaped β -cyclodextrin molecule. © 1990, American Chemical Society. All rights reserved.

引用

页码：940 / 944

页数：5

共 19 条

[1]

Bender M. L., 1978, CYCLODEXTRIN CHEM, DOI [10.1007/978-3-642-66842-5, DOI 10.1007/978-3-642-66842-5]

[2] HYDROGEN BONDING AND CONFORMATION OF GLUCOSE AND POLYGLUCOSES IN DIMETHYLSULPHOXIDE SOLUTION [J].