SERENDIPITOUS SYNTHESIS OF DIAXIAL 2,4-DIPHENYL-3,7-DIOXABICYCLO[3.3.0]OCTANE

被引：3

作者：

PELTER, A ^{[1
]}

WARD, RS ^{[1
]}

COLLINS, P ^{[1
]}

VENKATESWARLU, R ^{[1
]}

KAMAKSHI, C ^{[1
]}

机构：

[1] ANDHRA UNIV,POSTGRAD CTR,DEPT CHEM,NUZVID 521201,INDIA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)74260-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of cis-3,4-dibenzoyltetrahydrofuran with BMS, very surprisingly yields diaxial 2,4-diphenyl-3,7-dioxabicyclo[3.3.0]octane in a reaction that contrasts sharply with processes involving equilibrating benzylic carbocations which yield the diequatorial isomer.

引用

页码：4361 / 4364

页数：4

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