FACTORIZATION OF LIGAND-BASED REDUCTION POTENTIALS

被引：69

作者：

DODSWORTH, ES

VLCEK, AA

LEVER, ABP

机构：

[1] Department of Chemistry, York University, Ontario, M3J 1P3, North York

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1021/ic00084a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction potentials of a series of polypyridine complexes of Mo0, Os(II), Re(I), and Ru(II), some nitrosyl Os(II) and Ru(II) complexes, and a series of dinitrosylmolybdenum species are parametrized with the SIGMAE(L)(L) parameter. The slope, S(L), and intercept, I(L), of the linear correlations are shown to relate to metal-ligand coupling and interligand coupling through the metal center.

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页码：1045 / 1049

页数：5

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