ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY ON OXIDE-FILMS FORMED ON ZIRCALOY-4 IN HIGH-TEMPERATURE WATER

被引：64

作者：

BATAILLON, C

BRUNET, S

机构：

来源：

ELECTROCHIMICA ACTA | 1994年 / 39卷 / 03期

关键词：

OXIDE FILM; CAPACITANCE; CLUSTER; PH; IMPEDANCE SPECTROSCOPY;

D O I：

10.1016/0013-4686(94)80086-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Complex capacitance spectra obtained on oxide films formed by high temperature water oxidation of Zircaloy 4 exhibited dielectric losses which have been identified with those derived from the cluster model. The complex capacitance showed a Low Frequency Dispersion (LFD). A description of oxide film defects and defect transport are presented. The coupling between dynamic behaviour of defects and solution pH is shown.

引用

页码：455 / 465

页数：11

共 33 条

[1]

ARDIZZONE S, 1990, CROAT CHEM ACTA, V63, P545

[2]

BATAILLON C, 1991, EUROCORR 91 BUDAPEST, V2, P670

[3] CATIONIC SHORT-RANGE ORDER IN HOLLANDITE K1.54MG0.77T7.23O16 - EVIDENCE FOR IMPORTANCE OF ION-ION INTERACTIONS IN SUPERIONIC CONDUCTORS [J].