NONLINEAR-OPTICAL PROPERTIES OF POLYMERS BEARING PENDENT PHOSPHINE OXIDE CHROMOPHORES

被引：6

作者：

CHANECHING, K ^{[1
]}

LEQUAN, M ^{[1
]}

LEQUAN, RM ^{[1
]}

KAJZAR, F ^{[1
]}

机构：

[1] CENS,CEA,DTA,LETI,DEIN,SPE,PHYS ELECTR MAT LAB,F-91191 GIF SUR YVETTE,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 242卷 / 06期

关键词：

D O I：

10.1016/0009-2614(95)00761-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polymethacrylates and polyurethanes containing covalently bound organophosphorus NLO chromophores have been synthesized and characterized. These polymers contain a high concentration of NLO chromophores. Film samples obtained by spin coating and poled by the corona method show large second harmonic coefficients (d(33) = 70 to 135 pm V-1) measured at 1064 nm. The bulky size and the local polarity of the diphenylphosphoryl acceptor group contribute to the high glass transition temperature (T-g = 120 to 163 degrees C) and to the good temporal stability of these materials.

引用

页码：598 / 603

页数：6

共 19 条

[1] CROSS-LINKED POLYMER MATERIALS FOR NONLINEAR OPTICS .1. UV-CURED ACRYLIC-MONOMERS BEARING AZOBENZENE DYES [J].

BOOGERS, JAF ;

KLAASE, PTA ;

DEVLIEGER, JJ ;

ALKEMA, DPW ;

TINNEMANS, AHA .

MACROMOLECULES, 1994, 27 (01) :197-204

[2] PHOSPHINE OXIDES AS NOVEL ACCEPTOR GROUPS IN MOLECULES PRESENTING NONLINEAR-OPTICAL PROPERTIES [J].

CHANECHING, K ;

LEQUAN, M ;

LEQUAN, RM ;

RUNSER, C ;

BARZOUKAS, M ;

FORT, A .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (04) :649-652

[3] NOVEL 2ND-ORDER NONLINEAR OPTICAL POLYMERS VIA CHEMICAL CROSS-LINKING-INDUCED VITRIFICATION UNDER ELECTRIC-FIELD [J].

EICH, M ;

RECK, B ;

YOON, DY ;

WILLSON, CG ;

BJORKLUND, GC .

JOURNAL OF APPLIED PHYSICS, 1989, 66 (07) :3241-3247

[4] ISOCYANATE CROSS-LINKED POLYMERS FOR NONLINEAR OPTICS .1. POLYMERS DERIVED FROM 3-AMINO-5-[4'-(N-ETHYL-N-(2''-HYDROXYETHYL)AMINO)BENZYLIDENE]-RHODANINE [J].

FRANCIS, CV ;

WHITE, KM ;

BOYD, GT ;

MOSHREFZADEH, RS ;

MOHAPATRA, SK ;

RADCLIFFE, MD ;

TREND, JE ;

WILLIAMS, RC .

CHEMISTRY OF MATERIALS, 1993, 5 (04) :506-510

[5]

GADRET G, 1993, THESIS ORSAY

[6]

KAJZAR F, 1991, NATO ADV SCI I E-APP, V194, P403

[7] POLED POLYMERIC NONLINEAR OPTICAL-MATERIALS - EXCEPTIONAL 2ND HARMONIC-GENERATION TEMPORAL STABILITY OF A CHROMOPHORE-FUNCTIONALIZED POLYIMIDE [J].

LIN, JT ;

HUBBARD, MA ;

MARKS, TJ ;

LIN, WP ;

WONG, GK .

CHEMISTRY OF MATERIALS, 1992, 4 (06) :1148-1150

[8] LARGE STABLE 2ND-HARMONIC COEFFICIENTS IN AN AZO-DYE ATTACHED POLYMER ORIENTED BY CORONA POLING [J].

MARTINEZ, DR ;

KOCH, K ;

RATSAVONG, FK ;

CARLISLE, GO .

JOURNAL OF APPLIED PHYSICS, 1994, 75 (08) :4273-4275

[9] CASCADING IN OPTICAL 3RD-HARMONIC GENERATION BY CRYSTALLINE QUARTZ [J].

MEREDITH, GR .

PHYSICAL REVIEW B, 1981, 24 (10) :5522-5532

[10]

MULLER H, 1992, MAKROMOL CHEM-RAPID, V13, P289

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