TERNARY LIXTIO2 PHASES FROM INSERTION REACTIONS

被引：227

作者：

MURPHY, DW ^{[1
]}

CAVA, RJ ^{[1
]}

ZAHURAK, SM ^{[1
]}

SANTORO, A ^{[1
]}

机构：

[1] NBS,WASHINGTON,DC 20234

来源：

SOLID STATE IONICS | 1983年 / 9-10卷 / DEC期

关键词：

CRYSTALS - Structure - LITHIUM AND ALLOYS - Chemical Reactions - NEUTRON DIFFRACTION APPARATUS - Applications - SOLIDS - Ionic Conduction - TITANIUM OXIDES - Chemical Reactions;

D O I：

10.1016/0167-2738(83)90268-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithium insertion reactions in the various close packed TiO//2 frameworks is discussed. Preliminary neutron diffraction powder profile analysis data are presented for the lithium inserted anatase Li//0//. //5TiO//2, the spinel LiTi//2O//4, and the lithiated spinel Li//2Ti//2O//4. A simple model based on minimizing cation repulsion is used to rationalize the structures and diffusion of lithium.

引用

收藏

页码：413 / 417

页数：5

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