SYNTHESIS OF TRIFLUOROMETHYLALKENES AND ALKYNES - TRIFLUOROMETHYL CAPTODATIVE OLEFINS

被引：30

作者：

LAURENT, AJ ^{[1
]}

LEDREAN, IM ^{[1
]}

SELMI, A ^{[1
]}

机构：

[1] LAB CHIM SUBST NAT,1060 TUNIS,TUNISIA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 26期

关键词：

ETHYLTHIOTRIFLUOROMETHYLALDEHYDE; TRIFLUOROMETHYLALKYNES; CAPTODATIVE OLEFINS; DECARBONYLATION; NUCLEOPHILIC SUBSTITUTION;

D O I：

10.1016/0040-4039(91)80692-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

beta-ethylthio-beta-trifluoromethylketones 3 and aldehydes 4 are easily prepared from beta-chloroolefines 5 and 6. Trifluoromethylalkynes 7 and captodative alkenes 8 are obtained by reaction of KOH on aldehydes 6 or 4.

引用

页码：3071 / 3074

页数：4

共 11 条

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