SYNTHESIS AND STRUCTURE OF THE 1ST TELLURIUM(III) RADICAL CATION

被引：31

作者：

BJORGVINSSON, M ^{[1
]}

HEINZE, T ^{[1
]}

ROESKY, HW ^{[1
]}

PAUER, F ^{[1
]}

STALKE, D ^{[1
]}

SHELDRICK, GM ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 12期

关键词：

D O I：

10.1002/anie.199116771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first Te(III) radical cation 1 occurs as monomer in its AsF6 salt. This was proved for 1-AsF6, obtained unexpectedly from the reaction of Te(N(SiMe3)2)2 with AgAsF6 in the form of black crystals. The blue metastable solutions in CH2Cl2 and CHCl3 display only one broad ESR peak, showing that the unpaired electron occupies a p orbital on tellurium.

引用

页码：1677 / 1678

页数：2

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