NICKEL(I) (SALEN)-ELECTROCATALYZED REDUCTION OF BENZAL CHLORIDE

被引：54

作者：

FRY, AJ

FRY, PF

机构：

[1] Department of Chemistry, Wesleyan University, Middletown

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 13期

关键词：

D O I：

10.1021/jo00065a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrochemical reduction of nickel(II)(salen) (5) in the presence of benzal chloride (1) in dimethylformamide at a carbon cathode results in catalytic conversion of 1 into a variety of monomeric and dimeric products, depending upon experimental conditions. The mechanism of formation of the various products and the results of experiments designed to clarify these mechanisms are discussed.

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页码：3496 / 3501

页数：6

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